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Derek Harold Richard Barton [1918-1998] British
Rank: 107
Scientist, Chemist


Sir Derek Harold Richard Barton PhD FRS FRSE was an English organic chemist and Nobel Prize laureate for 1969.


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The first serious applications were in triterpenoid chemistry.
101
X-Ray crystallography is nowadays an accurate and rapid method of determining conformation in the crystal lattice, which conformation usually corresponds to the preferred conformation in solution.
102
It does not seem, however, that organic chemists were much worried about barriers to rotation in organic molecules in general at that time because there was no technique available to demonstrate the phenomenon experimentally.
103
Every chemical reaction has a transition state.
104
Many transition states have a well-defined preferred geometrical requirement.
105

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